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[外文期刊] Solvent-induced dual nucleophiles and the α-effect in the S_N2 versus E2 competition

作者： Xiangyu Wu¹;F Matthias Bickelhaupt^{2 3 4};Jing Xie¹; （¹ Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China. jingxie@bit.edu.cn. ² Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands. f.m.bickelhaupt@vu.nl. ³ Institute for Molecules and Materials (IMM), Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands. ⁴ Department of Chemical Sciences, University of Johannesburg, Auckland Park, Johannesburg 2006, South Africa.）

出处： Physical chemistry chemical physics : PCCP 2024

摘要： We have quantum chemically investigated how microsolvation affects the various E2 and S_N2 pathways, their mutual competition, and the α-eff ...

[外文期刊] Synthesis of π-Conjugated Chiral Aza/Boracyclophanes with a meta and para Substitution

作者： Kai Zhang;Mengyao Hao;Tianyun Jin;Yafei Shi;Guoqing Tian;Chenglong Li;Dr. Hongwei Ma;Dr. Niu Zhang;Prof. Dr. Quansong Li;Prof. Dr. Pangkuan Chen （Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China These authors contributed equally to this work. Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China Program in General Education, Capital Normal University, Beijing, 102488 China These authors contributed equally to this work. Center of Marine Biotechnology and Biomedicine, Scripps Institution of Oceanography, University of California, San Diego La Jolla, 92093 USA Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China Analysis & Testing Centre, Beijing Institute of Technology, Beijing, 102488 China Analysis & Testing Centre, Beijing Institute of Technology, Beijing, 102488 China Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488 China）

出处： Chemistry – A European Journal 2024 Vol.30 No.5 Pe202302950

关键词： π-Conjugated Macrocycles;Axial Chirality;Circularly Polarized Luminescence;Organoborane;Triarylamine

摘要： Graphical Abstract We report the synthesis of π-conjugated chiral aza/boracyclophanes that show unique dependence of the racemization energy barriers ...

[外文期刊] Synthesis of Trifluoromethylated Monoterpenes by an Engineered Cytochrome P450

作者： Feiyan Yuan;Jing Ding;Yiyang Sun;Prof. Dr. Jianhua Liang;Prof. Dr. Yunzi Luo;Dr. Yang Yu （Institute of Biochemical Engineering, Key Laboratory of, Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China Key Laboratory of Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China Institute of Biochemical Engineering, Key Laboratory of, Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China Key Laboratory of Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China Frontiers Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering (Ministry of Education), School of Chemical Engineering and Technology, Tianjin University, Tianjin, China. Institute of Biochemical Engineering, Key Laboratory of, Medical Molecule Science and Pharmaceutical Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China）

出处： Chemistry – A European Journal 2024 Vol.30 No.10 Pe202302936

关键词： Fluorinated compounds;Cyclopropanation;Biocatalysis;Carbene transfer;Monoterpenes

摘要： Graphical Abstract The carbene transfer reaction was realized in the biosynthetic pathway. Using L-limonene as the precursor, L-carveol was biotransfo ...

[外文期刊] Ionized water-soluble organic nanosheets with light/ultrasound dual excitation channels for efficient killing of multidrug-resistant bacteria

作者： Yufan Gu¹;Dayong Jiang²;Luoyi Wang²;Guangpeng Gao¹;Xu-Hui Jin¹; （¹ Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 100081, Beijing, P. R. China. xuhui.jin@bit.edu.cn. ² State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, 100101, Beijing, China.）

出处： Chemical communications (Cambridge, England) 2024

摘要： A novel ionized heavy-atom-free two-dimensional organic nanosheet was prepared and exhibited highly selective generation of singlet oxygen under both ...

[外文期刊] An extensive exploration of non-conventional sources for preparing NiS and its potential applications in battery and photodegradation processes

作者： Hussain, Wajid¹; Sulaman, Muhammad³; Sandali, Yahya⁴; Shahid Iqbal, Muhammad⁵; Guo, Honglian²; Li, Chuanbo²; Irfan, Ahmad⁶; Li, Hui¹ （¹Key Laboratory of Cluster Sciences of Ministry of Education Beijing Key Laboratory of Photoelectronic/ Electro Photonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing; 102488, China;²Optoelectronics Research Center, School of Science, Minzu University of China, Beijing; 100081, China;³Beijing Key Lab of Nanophotonics and Ultrafine Optoelectronic Systems, Center for Micro-Nanotechnology, Key Lab of Advanced Optoelectronic Quantum Design and Measurement, Ministry of Education, School of Physics, Beijing Institute of Technology, Beijing; 100081, China;⁴Physics Department, College of Science, University of Jeddah, Jeddah; 23890, Saudi Arabia;⁵Department of Physics, University of Agriculture, Faisalabad; 38000, Pakistan;⁶Department of Chemistry, College of Science, King Khalid University, PO Box 9004, Abha; 61413, Saudi Arabia）

出处： Materials Science and Engineering: B 2024

[外文期刊] Unveiling the impact of pore structure of cathode catalyst layer on proton exchange membrane cell performance

作者： Ni, Zhaojing¹; Wang, Lu¹; Wang, Bo¹ （¹Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, Frontiers Science Center for High Energy Material, Advanced Technology Research Institute (Jinan), School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing; 100081, China）

出处： International Journal of Hydrogen Energy 2024 P1404-1413

[外文期刊] Improving CO2-to-C2 Conversion of Atomic CuFONC Electrocatalysts through F, O-Codrived Optimization of Local Coordination Environment

作者： Lv, Zunhang¹; Wang, Changli¹; Liu, Yarong¹; Liu, Rui¹; Zhang, Fang¹; Feng, Xiao¹; Yang, Wenxiu¹; Wang, Bo¹ （¹Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing; 100081, China）

出处： Advanced Energy Materials 2024

[外文期刊] Adjacent Metal Atomic Pairs Within Atomically Dispersed Catalysts for Reaching a Synergistic Electrocatalytic CO2 Reduction: A Review

作者： Wang, Changli¹; Lv, Zunhang¹; Feng, Xiao¹; Yang, Wenxiu¹; Wang, Bo¹ （¹Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Materials Science and Engineering, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing; 100081, China）

出处： Advanced Energy Materials 2024

[外文期刊] Learning Rat-Like Behavioral Interaction Using a Small-Scale Robotic Rat

作者： Xie,Hongzhao¹²;Gao,Zihang¹²;Jia,Guanglu¹²;Shimoda,Shingo³;Shi,Qing¹²; （¹Intelligent Robotics Institute, School of Mechatronical Engineering, Beijing Institute of Technology, Beijing, 100081, China;²Key Laboratory of Biomimetic Robots and Systems, Beijing Institute of Technology, Ministry of Education, Beijing, 100081, China;³Nagoya University, Graduate School of Medicine, Nagoya, Japan）

出处： Cyborg and Bionic Systems 2023 Vol.4

摘要： In this paper, we propose a novel method for emulating rat-like behavioral interactions in robots using reinforcement learning. Specifically, we devel ...

[外文期刊] How and When Generalized Reciprocity and Negative Reciprocity Influence Employees Well-Being: The Moderating Role of Strength Use and the Mediating Roles of Intrinsic Motivation and Organizational Obstruction

作者： Zhu,Nan¹;Liu,Yuxin²;Zhang,Jianwei³; （¹School of Business Administration, Fujian Jiangxia University, No.2 Xiyuangong Road, University Town, Fuzhou, 350108, China;²Business School, University of International Business and Economics, Rm. 822, Keyan Building, No.10, Huixin Dongjie, Beijing, 100029, China;³School of Humanities and Social Science, Beijing Institute of Technology, Rm. 411, Zhongxin Teaching Building, 5 South Zhongguancun Street, Beijing, 100081, China）

出处： Behavioral Sciences 2023 Vol.13 No.6

摘要： Although the literature has shown that generalized reciprocity and negative reciprocity as exchange norms can significantly influence employees outcom ...