作者： 刘兵，张平敏，张黄，胡长文，韩洪亮，张英磊，郜芸，徐娇，孔凡萍，曹赛龙，张万鹏，金科，陈家林，王伯轩，田乐 （北京首创生态环保集团股份有限公司；北京首创北科环境科技研究院有限公司；北京工业大学环境与能源工程学院；北京理工大学；首都师范大学；天地科技股份有限公司）

出处： 环境化学 2024 第8期

关键词： 光催化；可见光；二氧化钛；球状金.

摘要： 利用溶胶凝胶法成功地制备出一种新型的核壳材料——Au@TiO₂.经过水热晶化，该材料可膨胀至300 nm，壳层TiO₂ 晶化为锐钛矿相，但核心球状Au 的形貌保持不变.采用粉末X 射线衍射技术（PXRD）、ZETA 电位、高分辨透射电子显微镜（HRTEM） ...

作者： Gao,Zongyin¹;Yang,Guoping⁵;Dong,Jing²;Liu,Ping³;Yu,Fei³⁴;Li,Zhen¹;Zhang,Yalin¹;Zhang,Meiyu¹;Huang,Xianqiang¹;Hu,Changwen⁶; （¹Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng, 252059, China;²College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing, 100048, China;³Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China;⁴State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, China;⁵School of Chemistry, Biology and Material Science, Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang, 330013, China;⁶Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China）

出处： Journal of Catalysis 2024 Vol.429

摘要： The controlled synthesis and exploration of the biomass valorization properties of organo-functionalized ionic-type polyoxometalates has been attracti ...

作者： Di Zhang¹;Changan Wang¹;Zhengguo Lin²;Long-Zhang Dong³;Chao Zhang⁴;Zishuo Yao¹;Peng Lei¹;Jing Dong¹;Jianxin Du¹;Yingnan Chi¹;Ya-Qian Lan⁵;Changwen Hu¹; （¹ Beijing Institute of Technology, School of Chemistry, CHINA. ² Hebei Normal University, School of Chemistry, CHINA. ³ South China Normal University, School of Chemistry, CHINA. ⁴ Henan University, School of Chemistry, CHINA. ⁵ South China Normal University, school of chemistry, No. 378, Waihuan West Road, Panyu District, 510006, Guangzhou, CHINA.）

出处： Angewandte Chemie (International ed. in English) 2024 Pe202320036

关键词： fullerene-like metal-oxo cluster;niobovanadate;pentagonal structural motif;polyoxovanadate cage.

摘要： The striking aesthetic appeal of fullerene-like clusters has captured the interest of researchers. Nevertheless, the assembly of fullerene-like polyox ...

作者： Bing,Liu¹²;Huang,Zhang³;Hongliang,Han⁴;Changwen,Hu⁵;Yinglei,Zhang¹²; （¹Beijing Capital Eco⁃Environment Protection Group Co., Ltd., Beijing, 100037, China;²Beijing Capital Beike Environmental Technology Research Institute Co., Ltd., Beijing, 100044, China;³College of Environment and Energy Engineering, Beijing University of Technology, Beijing, 100124, China;⁴Department of Chemistry, Capital Normal University, Beijing, 100089, China;⁵College of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102401, China）

出处： Chinese Journal of Inorganic Chemistry 2024 Vol.40 No.5 P941-952

摘要： TiO2‐coated triangle Au with a core‐shell structure (Au@TiO2) was synthesized using the sol‐gel method. After hydrothermal crystallization, the partic ...

作者： Li, Jikun¹;Ma, Junwei³;Wei, Chuanping¹;Zheng, Zebao¹;Han, Yinfeng¹;Wang, Huiping¹;Wang, Xueshen¹;Hu, Changwen² （¹Taishan Univ, Coll Chem & Chem Engn, Tai An 271021, Shandong, Peoples R China.;²Beijing Inst Technol, Beijing Key Lab Photoelect Electrophoton, Sch Chem, Key Lab Cluster Sci,Minist Educ, Beijing 100081, Peoples R China.;³Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China.）

出处： DALTON TRANSACTIONS 2024 Vol.53 No.10 P4492-4500

关键词： HYBRID POLYOXOVANADATES; HETEROGENEOUS CATALYSTS; CONTROLLABLE SYNTHESIS; OXIDATION; SULFOXIDATION; DECAVANADATE; CLUSTERS; PD

摘要： As important building blocks in natural products and organic synthesis, thioethers have a wide range of potential applications. Herein, polyoxometalat ...

作者： Dong, Jing¹;Zhang, Di²;Zhang, Peixuan²;Liu, Chengpeng²;Li, Jie²;Bai, Jing¹;Chi, Yingnan²;Hu, Changwen² （¹Beijing Technol & Business Univ, Sch Light Ind Sci & Engn, 11 Fucheng Rd, Beijing 100048, Peoples R China.;²Beijing Inst Technol, Sch Chem & Chem Engn, Key Lab Cluster Sci,Minist Educ, Beijing Key Lab Photoelect Electrophoton Convers M, Beijing 100081, Peoples R China.）

出处： COORDINATION CHEMISTRY REVIEWS 2024 Vol.517

关键词： METAL-ORGANIC FRAMEWORKS; CATALYTICALLY ACCESSIBLE POLYOXOMETALATE; CATIONIC SILICA NANOPARTICLES; DETOXIFYING SULFUR MUSTARD; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; HETEROGENEOUS CATALYSTS; HIGHLY EFFICIENT; HYDROLYTIC DECONTAMINATION; PHYSICOCHEMICAL PROPERTIES

摘要： The rampant misuse of chemical warfare agents (CWAs) poses a grave threat to the safety of both military personnel and civilians. Therefore, the effec ...

作者： Geng, Weijie¹;Zhang, Di¹;Zhen, Ni¹;Du, Jianxin²;Dong, Jing³;Liu, Chengpeng¹;Chen, Shi-Lu¹;Chi, Yingnan¹;Hu, Changwen¹ （¹Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Photoelectro Electrophoton Convers, Key Lab Cluster Sci,Minist Educ, Beijing 100081, Peoples R China.;²Beijing Inst Technol, Anal & Testing Ctr, Beijing 100081, Peoples R China.;³Beijing Technol & Business Univ, Sch Light Ind Sci & Engn, Beijing 100048, Peoples R China.）

出处： ACS CATALYSIS 2024 Vol.14 No.13 P10040-10052

关键词： COORDINATION POLYMERS; BIOMASS; HYDROGENATION; BENZALDEHYDE; DERIVATIVES; STRATEGIES; REDUCTION; ENERGIES; ACID

摘要： The electrochemical coupling of biomass platform molecules to biofuels provides a promising method for addressing energy crises and environmental issu ...

作者： Yu-Feng Liu¹;，Chang-Wen Hu²;，Guo-Ping Yang¹; （¹Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology；²Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology）

出处： Chinese Chemical Letters 2023 第34卷 第5期 P174-185

关键词： Polyoxometalates；Acid；catalysis；C–C；bond；formation；C–N；bond；formation；C–O；bond；formation；Heterocyclic；synthesis；Cyanosilylation；and；hydrolysis；reactions

摘要： Polyoxometalates（POMs） have conducive properties such as controlled Br?nsted and Lewis acidity, high thermal stability, nontoxic nature, tunable solub ...

作者： Yu-Feng Liu，Chang-Wen Hu，Guo-Ping Yang （Jiangxi Province Key Laboratory of Synthetic Chemistry，Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation，East China University of Technology，Nanchang 330013，China；Key Laboratory of Cluster Science of Ministry of Education，Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials，School of Chemistry and Chemical Engineering，Beijing Institute of Technology，Beijing 100081，China）

出处： 中国化学快报(英文版) 2023 第34卷 第5期 P143-154

关键词： Polyoxometalates；Acid catalysis；C-C bond formation；C-N bond formation；C-O bond formation；Heterocyclic synthesis；Cyanosilylation and hydrolysis reactions

摘要： Polyoxometalates(POMs)have conducive properties such as controlled Br?nsted and Lewis acidity,high thermal stability,nontoxic nature,tunable solubilit ...

作者： Jikun Li¹;Chuanping Wei¹;Yinfeng Han¹;Changwen Hu²; （¹ College of Chemistry and Chemical Engineering, Taishan University, Tai\'an, 271021, Shandong, P. R. China. lijk0212@163.com. ² Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, P.R. China. cwhu@bit.edu.cn.）

出处： Dalton transactions (Cambridge, England : 2003) 2023

摘要： Polyoxovanadates (POVs) have received widespread attention in catalytic applications due to their various structures and remarkable redox properties. ...