作者:Dong, Yalu;Peng, Panpan;Hu, Baoping;Su, Hui;Li, Shenghua;Pang, Siping (School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. mrmichelle@163.com. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. double_pan_peng@163.com. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. m18811301152@163.com. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. a178541@126.com. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. lishenghua@bit.edu.cn. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China. pangsp@bit.edu.cn.)
出处:Molecules 2017
关键词:energetic materials;metal organic frameworks;densities;polynitro heterocyclic ligands
摘要:High-energy metal-organic frameworks (MOFs) based on nitrogen-rich ligands are an emerging class of explosives, and density is one of the positive fac ...
作者:Shangbiao Feng;Baoseng Zhang;Chunwang Luo;Yang Liu;Shuangfei Zhu;Ruijun Gou;Shuhai Zhang;Ping Yin;Siping Pang (1School of Environmental and Safety Engineering, North University of China, Taiyuan 030051, China;2School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;3Beijing Institute of Technology Chongqing Innovation Center, Chongqing 401120, China)
出处:Organic Letters 2023
摘要:A gem-dinitromethyl group was successfully introduced into the TNBI·2H2O structure (TNBI: 4,4′,5,5′-tetranitro-2,2′-bi-1H-imidazole) to obt ...
作者:Sun, Haiyun;Zhang, Xing;Wang, Jingqi;Jiang, Rongpei;Fang, Tao;Li, Yuchuan;Pang, Siping (1Beijing Key Laboratory of Research and Application for Aerospace Green Propellants, Beijing Institute of Aerospace Testing Technology, Fengtai District, Beijing, 100074, China;2School of Materials Science & Engineering, Beijing Institute of Technology, South Street No. 5, Zhongguancun Haidian District, Beijing, 100081, China)
出处:Propellants, Explosives, Pyrotechnics 2022
关键词:KINETICS
摘要:1,2-Dicyclopropyl-1-methyl cyclopropane (DMCP) was found a high-energy liquid hydrocarbon propellant. A model combustion chamber was designed and manu ...
作者:Alexander A. Larin1;Ivan V. Ananyev2,3;Ekaterina V. Dubasova3,4;Fedor E. Teslenko1;Konstantin A. Monogarov5;Dmitry V. Khakimov1;Chun-lin He6;Si-ping Pang6;Galina A. Gazieva1;Leonid L. Fershtat1;
出处:Energetic Materials Frontiers 2022
关键词:Nitrogen heterocycles;Energetic materials;1,2,5-Oxadiazoles;Mechanical sensitivity;Electrostatic potential
摘要:Two novel representatives of energetic (1,2,4-triazolyl)furoxans were prepared from the readily available (furoxanyl)amidrazones. Synthesized compound ...
发明人:李生华,荣宇佳,薛少敏,庞思平
申请日期:2022.04.14
摘要:本发明涉及一种溴代烷烃的高选择性分离方法,特别涉及一种溴丙烷、溴丁烷、溴戊烷同分异构体的高选择性分离方法,属于吸附分离领域。本发明的方法使用了一种新培养的乙氧基柱[5]芳烃与4‑硝基邻苯二甲腈所形成的共晶晶体材料,通过固体蒸汽吸附的方法实现溴代烷烃同分异构体的高选择性分离。本方法操作简单,能耗低、所 ...
发明人:李冠男,李生华,庞思平
申请日期:2022.09.02
摘要:本发明涉及一种固载酶的富氮基金属有机骨架材料及其制备方法,属于生物材料技术领域。本发明的目的是为了解决现有催化剂适用范围窄、酸性条件下不稳定的问题,通过“一锅”封装的原位生长法,进行富氮基金属有机骨架材料固载多酶的反应,构筑得到具有催化功能的复合材料;该骨架用于单酶、双酶及多酶的定位组装。该方法结合 ...
发明人:李生华,魏子皓,李亚琼,薛少敏,庞思平
申请日期:2022.09.28
摘要:本发明涉及一种纤维素‑MOF核壳结构的制备方法及应用,属于光还原二氧化碳反应的高效催化剂领域。本发明的纤维素‑MOF核壳结构,微观形貌为亚纳米秸秆状结构;由内核和内核外的外壳构成,所述内核为MOF,所述外壳为醋酸纤维素。制备方法为:将ZrCl4、卟啉四羧酸和醋酸纤维素溶解在DMF中,在室温下搅拌一段 ...
发明人:尹平,谢文杰,庞思平
申请日期:2022.08.18
摘要:本发明提供一种多硝基富氮含能化合物,所述多硝基富氮含能化合物为1,1\'(1,2二氮烯基)双(5甲基3,4二硝基1H吡唑)含能化合物,结构式如式Ⅰ所示: 通过将5甲基3硝基吡唑在发烟硫酸和浓硝酸作用下进行硝化并与THA进行氨化反应后,加入次氯酸叔丁酯或是二氯异氰尿酸钠与乙酸的混合物反应得到1,1\' ...
发明人:何春林,贾宏福,庞思平
申请日期:2022.09.22
摘要:本发明公开了掺杂型自燃离子液体,其通过添加改性添加物,在一定程度上缩短点火延迟时间,同时可以提高燃烧的火焰强度和持续时间,而且这种添加物形成的自燃离子液体稳定性较好,长时间存放不存在沉降的问题。本发明还公开了掺杂型自燃离子液体的制备方法,其通过简单的混合搅拌,获得澄清溶液状的掺杂型自燃离子液体,通过 ...
发明人:尹平,谢昌鹏,庞思平
申请日期:2022.08.18
摘要:本发明提供一种四嗪稠环含能化合物,结构式如式Ⅰ所示: 以联咪唑作为原料,通过选择性硝化反应后将得到的4,4\'二硝基1H,1\'H2,2\'联咪唑加入磷酸二氢钾和氢氧化钾,搅拌完全后缓慢加入羟胺O磺酸,反应完成后过滤干燥并充分溶解于乙酸乙酯中,滴加次氯酸叔丁酯,反应结束后加入1%的碳酸氢钠水溶液洗涤 ...